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Issue 38, 2011
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Reverse orthogonal strategy for oligosaccharide synthesis

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Abstract

Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction.

Graphical abstract: Reverse orthogonal strategy for oligosaccharide synthesis

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Publication details

The article was received on 09 Jun 2011, accepted on 16 Aug 2011 and first published on 05 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC13409D
Chem. Commun., 2011,47, 10602-10604

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    Reverse orthogonal strategy for oligosaccharide synthesis

    K. Fujikawa, N. V. Ganesh, Y. H. Tan, K. J. Stine and A. V. Demchenko, Chem. Commun., 2011, 47, 10602
    DOI: 10.1039/C1CC13409D

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