Issue 32, 2011

A novel low density metal–organic framework with pcu topology by dendritic ligand

Abstract

A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn4O(CO2)6 units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H2 uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.

Graphical abstract: A novel low density metal–organic framework with pcu topology by dendritic ligand

Supplementary files

Article information

Article type
Communication
Submitted
17 May 2011
Accepted
01 Jul 2011
First published
13 Jul 2011

Chem. Commun., 2011,47, 9167-9169

A novel low density metal–organic framework with pcu topology by dendritic ligand

J. Jia, F. Sun, Q. Fang, X. Liang, K. Cai, Z. Bian, H. Zhao, L. Gao and G. Zhu, Chem. Commun., 2011, 47, 9167 DOI: 10.1039/C1CC12891D

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