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Issue 31, 2011
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Acceleration of the through space S1 energy transfer rates in cofacial bisporphyrin bio-inspired models by virtue of substituents effect on the Förster J integral and its implication in the antenna effect in the photosystems

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Abstract

The singlet kET for cofacial β-octaalkylporphyrin/bis(meso-aryl)porphyrin dyads increases linearly with the gap between the donor–acceptor 0–0 fluorescence peaks at 77 K.

Graphical abstract: Acceleration of the through space S1 energy transfer rates in cofacial bisporphyrin bio-inspired models by virtue of substituents effect on the Förster J integral and its implication in the antenna effect in the photosystems

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Publication details

The article was received on 14 May 2011, accepted on 27 Jun 2011 and first published on 11 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12839F
Citation: Chem. Commun., 2011,47, 8817-8819
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    Acceleration of the through space S1 energy transfer rates in cofacial bisporphyrin bio-inspired models by virtue of substituents effect on the Förster J integral and its implication in the antenna effect in the photosystems

    J. Camus, S. M. Aly, C. Stern, R. Guilard and P. D. Harvey, Chem. Commun., 2011, 47, 8817
    DOI: 10.1039/C1CC12839F

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