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Issue 28, 2011
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A new insight into ortho-(dimesitylboryl)diphenylphosphines: applications in Pd-catalyzed Suzuki–Miyaura couplings and evidence for secondary π-interaction

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Abstract

ortho-(Dimesitylboryl)phenylphosphines 1 and 2 were applied in Pd-catalyzed Suzuki–Miyaura C–C couplings. Coordination studies were performed in order to rationalize the relationship between structure and reactivity. Full characterization of a Pd(0) complex derived from 1 has evidenced a new coordination mode for phosphine-arylboranes involving secondary π-interaction between one of the mesityl groups at boron and the metal centre.

Graphical abstract: A new insight into ortho-(dimesitylboryl)diphenylphosphines: applications in Pd-catalyzed Suzuki–Miyaura couplings and evidence for secondary π-interaction

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Article information


Submitted
04 May 2011
Accepted
24 May 2011
First published
20 Jun 2011

Chem. Commun., 2011,47, 8163-8165
Article type
Communication

A new insight into ortho-(dimesitylboryl)diphenylphosphines: applications in Pd-catalyzed Suzuki–Miyaura couplings and evidence for secondary π-interaction

R. Malacea, N. Saffon, M. Gómez and D. Bourissou, Chem. Commun., 2011, 47, 8163
DOI: 10.1039/C1CC12611C

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