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Issue 30, 2011
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Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

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Abstract

In the presence of gold(I)–phosphine catalysts, alkenyl- and arylsilanes undergo intramolecular cyclisation reactions onto appendant alkyne moieties to afford 1-silaindene derivatives. The reaction pathways vary depending on the substituent on silicon.

Graphical abstract: Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

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Publication details

The article was received on 27 Apr 2011, accepted on 21 Jun 2011 and first published on 02 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12457A
Chem. Commun., 2011,47, 8697-8699

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    Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

    T. Matsuda, Y. Yamaguchi, M. Shigeno, S. Sato and M. Murakami, Chem. Commun., 2011, 47, 8697
    DOI: 10.1039/C1CC12457A

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