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Issue 35, 2011
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Encoded dendrimers with defined chiral composition via ‘click’ reaction of enantiopure building blocks

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Abstract

Dendrimers with end-groups of defined chiral composition have been prepared from alkyne functional enantio-pure building blocks obtained by selective enzymatic (ADH) ketone reductions using click chemistry. Optical rotation and enantioselective enzymatic modification is in agreement with the chiral composition of the dendrimers and permits unique molecular-level encoding of stereoisomeric dendritic libraries.

Graphical abstract: Encoded dendrimers with defined chiral composition via ‘click’ reaction of enantiopure building blocks

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Supplementary files

Article information


Submitted
26 Apr 2011
Accepted
08 Jul 2011
First published
26 Jul 2011

Chem. Commun., 2011,47, 9870-9872
Article type
Communication

Encoded dendrimers with defined chiral composition via ‘click’ reaction of enantiopure building blocks

B. Yeniad, H. Naik, R. J. Amir, C. E. Koning, C. J. Hawker and A. Heise, Chem. Commun., 2011, 47, 9870
DOI: 10.1039/C1CC12434J

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