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Issue 29, 2011
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Enantioselective [2+2+2] cycloaddition of ketenes and carbon disulfide catalyzed by N-heterocyclic carbenes

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Abstract

The chiral N-heterocyclic carbene-catalyzed [2+2+2] cycloaddition of ketenes and carbon disulfide was realized to give the cycloadduct of 1,3-oxathian-6-ones in good yields with excellent enantioselectivities.

Graphical abstract: Enantioselective [2+2+2] cycloaddition of ketenes and carbon disulfide catalyzed by N-heterocyclic carbenes

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Article information


Submitted
21 Apr 2011
Accepted
11 May 2011
First published
03 Jun 2011

Chem. Commun., 2011,47, 8388-8390
Article type
Communication

Enantioselective [2+2+2] cycloaddition of ketenes and carbon disulfide catalyzed by N-heterocyclic carbenes

X. Wang, L. Shen and S. Ye, Chem. Commun., 2011, 47, 8388
DOI: 10.1039/C1CC12316E

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