Issue 29, 2011

Enantioselective [2+2+2] cycloaddition of ketenes and carbon disulfide catalyzed by N-heterocyclic carbenes

Abstract

The chiral N-heterocyclic carbene-catalyzed [2+2+2] cycloaddition of ketenes and carbon disulfide was realized to give the cycloadduct of 1,3-oxathian-6-ones in good yields with excellent enantioselectivities.

Graphical abstract: Enantioselective [2+2+2] cycloaddition of ketenes and carbon disulfide catalyzed by N-heterocyclic carbenes

Supplementary files

Article information

Article type
Communication
Submitted
21 Apr 2011
Accepted
11 May 2011
First published
03 Jun 2011

Chem. Commun., 2011,47, 8388-8390

Enantioselective [2+2+2] cycloaddition of ketenes and carbon disulfide catalyzed by N-heterocyclic carbenes

X. Wang, L. Shen and S. Ye, Chem. Commun., 2011, 47, 8388 DOI: 10.1039/C1CC12316E

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