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Issue 27, 2011
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Total synthesis of (±)-chamobtusin A

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The total synthesis of chamobtusin A, the first diterpenoid alkaloid isolated from the whole Pinales, is described. Key features of the synthesis include a stereoselective intramolecular Michael addition to install a key stereocenter and an oxidative manipulation to prepare a 2H-pyrrole ring.

Graphical abstract: Total synthesis of (±)-chamobtusin A

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The article was received on 19 Apr 2011, accepted on 18 May 2011 and first published on 01 Jun 2011

Article type: Communication
DOI: 10.1039/C1CC12267C
Chem. Commun., 2011,47, 7878-7879

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    Total synthesis of (±)-chamobtusin A

    H. Suzuki and S. Aoyagi, Chem. Commun., 2011, 47, 7878
    DOI: 10.1039/C1CC12267C

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