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Issue 37, 2011
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Zn-containing porphyrin as a biomimetic light-harvesting molecule for biocatalyzed artificial photosynthesis

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Abstract

Among the porphyrin molecules with different metal insertion sites and functional ligands, Zn-porphyrin most efficiently regenerates NADH through photo-induced electron transfer in the presence of [Cp*Rh(bpy)H2O]2+, a rhodium-based electron mediator. Photochemical regeneration of NADH by Zn-porphyrin is successfully coupled with redox enzymatic synthesis under dark state conditions.

Graphical abstract: Zn-containing porphyrin as a biomimetic light-harvesting molecule for biocatalyzed artificial photosynthesis

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Article information


Submitted
18 Apr 2011
Accepted
24 Jun 2011
First published
11 Jul 2011

Chem. Commun., 2011,47, 10227-10229
Article type
Communication

Zn-containing porphyrin as a biomimetic light-harvesting molecule for biocatalyzed artificial photosynthesis

J. H. Kim, S. H. Lee, J. S. Lee, M. Lee and C. B. Park, Chem. Commun., 2011, 47, 10227
DOI: 10.1039/C1CC12222C

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