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Issue 27, 2011
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A regio- and stereoselective synthesis of trisubstituted alkenesviagold(i)-catalyzed hydrophosphoryloxylation of haloalkynes

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Abstract

A new stereoselective synthesis of trisubstituted alkenes is developed. Hydrophosphoryloxylation of haloalkynes provides Z-alkenyl halophosphates, which undergo Pd-catalyzed consecutive cross-coupling reactions to afford regio- and stereodefined trisubstituted alkenes.

Graphical abstract: A regio- and stereoselective synthesis of trisubstituted alkenesviagold(i)-catalyzed hydrophosphoryloxylation of haloalkynes

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Article information


Submitted
11 Apr 2011
Accepted
24 May 2011
First published
06 Jun 2011

Chem. Commun., 2011,47, 7851-7853
Article type
Communication

A regio- and stereoselective synthesis of trisubstituted alkenesviagold(I)-catalyzed hydrophosphoryloxylation of haloalkynes

B. C. Chary, S. Kim, D. Shin and P. H. Lee, Chem. Commun., 2011, 47, 7851
DOI: 10.1039/C1CC12052B

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