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Issue 21, 2011
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Design and synthesis of new chiral phosphorus–olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines

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Abstract

Novel chiral phosphorus–olefin bidentate ligands have been synthesized in a few steps from a readily available enantiopure compound. These ligands have been applied to a rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl aldimines, achieving high yield and enantioselectivity.

Graphical abstract: Design and synthesis of new chiral phosphorus–olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines

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Article information


Submitted
31 Mar 2011
Accepted
12 Apr 2011
First published
03 May 2011

Chem. Commun., 2011,47, 6123-6125
Article type
Communication

Design and synthesis of new chiral phosphorus–olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines

R. Shintani, R. Narui, Y. Tsutsumi, S. Hayashi and T. Hayashi, Chem. Commun., 2011, 47, 6123
DOI: 10.1039/C1CC11823D

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