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Issue 25, 2011
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Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

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Abstract

1,1′-Bis(trifluorovinyl)ferrocene is obtained in excellent yields from a Negishi type coupling reaction. Under certain redox conditions and in the presence of a suitable nucleophile, the highly reactive compound undergoes a transformation to fluorinated ferrocenophanes. Intra and intermolecular [2+2]-cycloaddition products are formed upon heating.

Graphical abstract: Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

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Publication details

The article was received on 30 Mar 2011, accepted on 06 May 2011 and first published on 25 May 2011


Article type: Communication
DOI: 10.1039/C1CC11812A
Citation: Chem. Commun., 2011,47, 7239-7241
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    Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

    M. Roemer and D. Lentz, Chem. Commun., 2011, 47, 7239
    DOI: 10.1039/C1CC11812A

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