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Issue 25, 2011
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Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

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Abstract

1,1′-Bis(trifluorovinyl)ferrocene is obtained in excellent yields from a Negishi type coupling reaction. Under certain redox conditions and in the presence of a suitable nucleophile, the highly reactive compound undergoes a transformation to fluorinated ferrocenophanes. Intra and intermolecular [2+2]-cycloaddition products are formed upon heating.

Graphical abstract: Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

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Article information


Submitted
30 Mar 2011
Accepted
06 May 2011
First published
25 May 2011

Chem. Commun., 2011,47, 7239-7241
Article type
Communication

Autocatalytic formation of fluorinated ferrocenophanes from 1,1′-bis(trifluorovinyl)ferrocene

M. Roemer and D. Lentz, Chem. Commun., 2011, 47, 7239
DOI: 10.1039/C1CC11812A

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