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Abstract | Cited by

The CF3 radical was generated from the reaction of S-(trifluoromethyl)diphenylsulfonium triflate with Na2S2O4 or HOCH2SO2Na under suitable conditions without further reduction. Based on this, a method for the synthesis of α-trifluoromethylated ketones has been successfully developed.

Graphical abstract: Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

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