Issue 20, 2011
From the journal:

Chemical Communications

“On water” sp3–sp2 cross-couplings between benzylic and alkenyl halides†

Valeria Krasovskaya,a   Arkady Krasovskiy,a   Anish Bhattacharjyaa  and  Bruce H. Lipshutz*a  

* Corresponding authors

a Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA
E-mail: lipshutz@chem.ucsb.edu
Fax: (805) 893-8265
Tel: (805) 893-2521

Abstract

Organic-solvent-free cross-couplings between benzylic and alkenyl halides have been developed. Various alkenyl halides can be efficiently benzylated by combining the precursor halides in the presence of Zn dust and a Pd catalyst at room temperature, in water as the only medium.

Graphical abstract: “On water” sp3–sp2 cross-couplings between benzylic and alkenyl halides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC11087J
Article type
Communication
Submitted
23 Feb 2011
Accepted
18 Mar 2011
First published
12 Apr 2011

Chem. Commun., 2011,47, 5717-5719

Permissions

Request permissions

“On water” sp3–sp2 cross-couplings between benzylic and alkenyl halides

V. Krasovskaya, A. Krasovskiy, A. Bhattacharjya and B. H. Lipshutz, Chem. Commun., 2011, 47, 5717 DOI: 10.1039/C1CC11087J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements