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Issue 18, 2011
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Pd(0)/Au(i) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(i)-complexes

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Abstract

A Pd(II)-catalyzed homo-coupling of Au(I)-aryls is reported. The reaction is driven by a Pd(0)/Au(I) redox reaction that generates a gold mirror and Pd(II), and illustrates one of the challenges for developing dual catalytic Au–Pd systems.

Graphical abstract: Pd(0)/Au(i) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(i)-complexes

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Publication details

The article was received on 22 Feb 2011, accepted on 17 Mar 2011 and first published on 31 Mar 2011


Article type: Communication
DOI: 10.1039/C1CC11055A
Chem. Commun., 2011,47, 5172-5174

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    Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes

    D. Weber and M. R. Gagné, Chem. Commun., 2011, 47, 5172
    DOI: 10.1039/C1CC11055A

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