Issue 19, 2011
From the journal:

Chemical Communications

Direct dendronization of polystyrenes using dendritic diarylcarbenium ion pools†

Toshiki Nokami,a   Takashi Watanabe,a   Naoki Musya,a   Tatsuya Morofuji,a   Kazukuni Tahara,b   Yoshito Tobeb  and  Jun-ichi Yoshida*a  

* Corresponding authors

a Department of Synthetic and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, 615-8510 Kyoto, Japan
E-mail: yoshida@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2725
Tel: +81-75-383-2726

b Division of Frontier Materials Science, Graduate School of Engineering Science, Osaka University, Toyonaka, 560-8531 Osaka, Japan
E-mail: tobe@chem.es.osaka-u.ac.jp
Fax: +81-6-6850-6229
Tel: +81-6-6850-6225

Abstract

Dendritic diarylcarbenium ions exhibited sufficient electrophilicity to react with unfunctionalized polystyrenes. The polymers obtained by the reaction of the first and the second generation dendritic diarylcarbenium ions with polystyrenes were well characterized by MALDI-TOF MS and SEC-MALLS analyses and observed by AFM.

Graphical abstract: Direct dendronization of polystyrenes using dendritic diarylcarbenium ion pools

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Article information

DOI
https://doi.org/10.1039/C1CC10923E
Article type
Communication
Submitted
16 Feb 2011
Accepted
21 Mar 2011
First published
04 Apr 2011

Chem. Commun., 2011,47, 5575-5577

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Direct dendronization of polystyrenes using dendritic diarylcarbenium ion pools

T. Nokami, T. Watanabe, N. Musya, T. Morofuji, K. Tahara, Y. Tobe and J. Yoshida, Chem. Commun., 2011, 47, 5575 DOI: 10.1039/C1CC10923E

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