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Issue 20, 2011
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Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

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Abstract

Reductions of chiral ketimines effected under H2 by catalytic amounts of B(C6F5)3 result in moderate to excellent diastereoselectivities. In the case of camphor and menthone derived imines, the reductions proceeded with greater than 95% diastereoselectivity.

Graphical abstract: Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

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Supplementary files

Article information


Submitted
22 Jan 2011
Accepted
31 Mar 2011
First published
18 Apr 2011

Chem. Commun., 2011,47, 5729-5731
Article type
Communication

Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

Z. M. Heiden and D. W. Stephan, Chem. Commun., 2011, 47, 5729
DOI: 10.1039/C1CC10438A

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