Issue 18, 2011
From the journal:

Chemical Communications

Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium†

Josué D. Mota-Morales,‡ab   María C. Gutiérrez,b   Isaac C. Sanchez,c   Gabriel Luna-Bárcenas*a  and  Francisco del Monte*b  

* Corresponding authors

a Centro de Investigación y Estudios Avanzados (CINVESTAV) Unidad Querétaro, Libramiento Norponiente 2000, Querétaro, QRO., México
E-mail: gluna@qro.cinvestav.mx
Fax: +52 4422119939
Tel: +52 4422119900

b Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), Cantoblanco 28049, Madrid, Spain
E-mail: delmonte@icmm.csic.es
Fax: +34 913720623
Tel: +34 913349033

c Department of Chemical Engineering, The University of Texas at Austin, Austin, USA

Abstract

Deep Eutectic Solvents (DESs) based upon mixtures of Acrylic Acid (AA) or Methacrylic Acid (MAA) and Choline Chloride (CCl) demonstrated superior performance than regular organic solvents and even ionic liquids for frontal polymerizations (FPs). Full recovering of CCl after FP provided an interesting green character to the process.

Graphical abstract: Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium

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Article information

DOI
https://doi.org/10.1039/C1CC10391A
Article type
Communication
Submitted
20 Jan 2011
Accepted
18 Mar 2011
First published
01 Apr 2011

Chem. Commun., 2011,47, 5328-5330

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Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium

J. D. Mota-Morales, M. C. Gutiérrez, I. C. Sanchez, G. Luna-Bárcenas and F. del Monte, Chem. Commun., 2011, 47, 5328 DOI: 10.1039/C1CC10391A

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