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Issue 13, 2011
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Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

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Abstract

Access to planar chiral complexes has been sought by catalytic desymmetrisation of a prochiral complex via asymmetric Suzuki–Miyaura cross-coupling. High selectivities of up to 98% ee were achieved using a bulky chiral palladium catalyst.

Graphical abstract: Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

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Publication details

The article was received on 18 Jan 2011, accepted on 10 Feb 2011 and first published on 28 Feb 2011


Article type: Communication
DOI: 10.1039/C1CC10347D
Chem. Commun., 2011,47, 3739-3741

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    Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

    X. Urbaneja, A. Mercier, C. Besnard and E. P. Kündig, Chem. Commun., 2011, 47, 3739
    DOI: 10.1039/C1CC10347D

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