CO2 selectivity of a 1D microporous adenine-based metal–organic framework synthesised in water

Kyriakos C. Stylianou; John E. Warren; Samantha Y. Chong; Jeremy Rabone; John Bacsa; Darren Bradshaw; Matthew J. Rosseinsky

doi:10.1039/C0CC05559J

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CO₂ selectivity of a 1D microporous adenine-based metal–organic framework synthesised in water†

Kyriakos C. Stylianou,^a John E. Warren,^a Samantha Y. Chong,^a Jeremy Rabone,^a John Bacsa,^a Darren Bradshaw^a and Matthew J. Rosseinsky*^a

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* Corresponding authors

^a Department of Chemistry, University of Liverpool, Crown Str., Liverpool L69 7ZD, UK
E-mail: m.j.rosseinsky@liverpool.ac.uk
Tel: +44 (0)151-7943499

Abstract

The coordination of adenine to Ni²⁺ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions viahydrogen bonding into a robust porous network. The material displays selectivity for CO₂ over CH₄ and an isosteric heat which increases with guest loading.

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Article information

DOI: https://doi.org/10.1039/C0CC05559J
Article type: Communication
Submitted: 14 Dec 2010
Accepted: 01 Feb 2011
First published: 17 Feb 2011

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Chem. Commun., 2011,47, 3389-3391

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CO₂ selectivity of a 1D microporous adenine-based metal–organic framework synthesised in water

K. C. Stylianou, J. E. Warren, S. Y. Chong, J. Rabone, J. Bacsa, D. Bradshaw and M. J. Rosseinsky, Chem. Commun., 2011, 47, 3389 DOI: 10.1039/C0CC05559J

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