Issue 13, 2011
From the journal:

Chemical Communications

Copper(ii)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides†

Wenhui Wang,a   Changduo Pan,b   Fan Chen*a  and  Jiang Cheng*a  

* Corresponding authors

a College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325000, People's Republic of China
E-mail: jiangcheng@wzu.edu.cn, fanchen@wzu.edu.cn

b Wenzhou Institute of Industry & Science, Wenzhou 325000, People's Republic of China

Abstract

Copper-catalyzed ortho-benzoxylation of 2-arylpyridine sp2 C–H bonds with acyl chloride is described. Notably, switching the base from t-BuOK to Li2CO3 causes chlorination of the C–H bond to take place.

Graphical abstract: Copper(ii)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides

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Article information

DOI
https://doi.org/10.1039/C0CC05557C
Article type
Communication
Submitted
14 Dec 2010
Accepted
14 Feb 2011
First published
28 Feb 2011

Chem. Commun., 2011,47, 3978-3980

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Copper(II)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides

W. Wang, C. Pan, F. Chen and J. Cheng, Chem. Commun., 2011, 47, 3978 DOI: 10.1039/C0CC05557C

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