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The first Ruddlesden–Popper type layered cobalt oxyfluoride, Sr2CoO3F, has been synthesized under a pressure of 6 GPa at 1700 °C and shown to adopt a K2NiF4-type structure with distorted square pyramidal coordination around Co and with O/F disorder at the apical sites.

Graphical abstract: New layered cobalt oxyfluoride, Sr2CoO3F

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