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Issue 9, 2011
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Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

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Abstract

The catalytic dehydrocoupling reaction of Me2NHBH3 with Al(NMe2)3 gives the dimer [Me2NBH2]2 and the chain [(Me2N)2BH], involving the thermally-stable AlIII hydride catalyst [{(Me2N)2BH2}2AlH].

Graphical abstract: Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

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Publication details

The article was received on 30 Nov 2010, accepted on 21 Dec 2010 and first published on 18 Jan 2011


Article type: Communication
DOI: 10.1039/C0CC05294A
Citation: Chem. Commun., 2011,47, 2682-2684
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    Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

    H. J. Cowley, M. S. Holt, R. L. Melen, J. M. Rawson and D. S. Wright, Chem. Commun., 2011, 47, 2682
    DOI: 10.1039/C0CC05294A

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