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Issue 9, 2011
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Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

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Abstract

The catalytic dehydrocoupling reaction of Me2NHBH3 with Al(NMe2)3 gives the dimer [Me2NBH2]2 and the chain [(Me2N)2BH], involving the thermally-stable AlIII hydride catalyst [{(Me2N)2BH2}2AlH].

Graphical abstract: Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

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Article information


Submitted
30 Nov 2010
Accepted
21 Dec 2010
First published
18 Jan 2011

Chem. Commun., 2011,47, 2682-2684
Article type
Communication

Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

H. J. Cowley, M. S. Holt, R. L. Melen, J. M. Rawson and D. S. Wright, Chem. Commun., 2011, 47, 2682
DOI: 10.1039/C0CC05294A

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