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Issue 11, 2011

Co and Mn polysiloxanes as unique initiator–catalyst-systems for the selective liquid phase oxidation of o-xylene

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Abstract

Co and Mn polysiloxanes are unique catalyst/initiator systems for the liquid phase oxidation of o-xylene showing higher activity than Co naphthenates, which is related to the weak interaction of the polar products with the hydrophobic surface as well as the absence of hydroxyl groups and surrounding oxygenates limiting radical quenching.

Graphical abstract: Co and Mn polysiloxanes as unique initiator–catalyst-systems for the selective liquid phase oxidation of o-xylene

Supplementary files

Article information


Submitted
19 Nov 2010
Accepted
12 Jan 2011
First published
28 Jan 2011

Chem. Commun., 2011,47, 3254-3256
Article type
Communication

Co and Mn polysiloxanes as unique initiator–catalyst-systems for the selective liquid phase oxidation of o-xylene

T. Förster, S. A. Schunk, A. Jentys and J. A. Lercher, Chem. Commun., 2011, 47, 3254 DOI: 10.1039/C0CC05050D

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