Issue 13, 2011
From the journal:

Chemical Communications

Is Se–Se bond cleavage the most favourable process in electron attachment to diselenides? The importance of asymmetry†‡

José A. Gámeza  and  Manuel Yáñez*a  

* Corresponding authors

a Departamento de Química, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Excelencia UAM-CSIC, Módulo 13, Cantoblanco, 28049-Madrid, Spain
E-mail: manuel.yanez@uam.es
Fax: +34 91-4975238

Abstract

Accurate ab initio calculations reveal that, in contrast with what has been commonly assumed up to now, electron attachment to diselenides does not always result in a Se–Se bond fission and, in general, the mechanism behind the bond fission may involve the crossing of several states.

Graphical abstract: Is Se–Se bond cleavage the most favourable process in electron attachment to diselenides? The importance of asymmetry

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Article information

DOI
https://doi.org/10.1039/C0CC04675B
Article type
Communication
Submitted
29 Oct 2010
Accepted
08 Feb 2011
First published
24 Feb 2011

Chem. Commun., 2011,47, 3939-3941

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Is Se–Se bond cleavage the most favourable process in electron attachment to diselenides? The importance of asymmetry

J. A. Gámez and M. Yáñez, Chem. Commun., 2011, 47, 3939 DOI: 10.1039/C0CC04675B

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