Issue 7, 2011
From the journal:

Chemical Communications

The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product†

Cornelia M. Mömming,a   Gerald Kehr,a   Roland Fröhlich‡a  and  Gerhard Erker*a  

* Corresponding authors

a Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster, Germany
E-mail: erker@uni-muenster.de
Fax: +49 251-83 36503

Abstract

The frustrated Lewis pair Mes2P–CH2CH2–B(C6F5)2 reacts with excess 6,6-dimethylpentafulvene to yield a P/B-Lewis pair addition product to an elusive pentafulvene [6 + 4] cycloaddition dimer. This observation may open a new field of utilization of frustrated Lewis pair chemistry.

Graphical abstract: The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product

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Article information

DOI
https://doi.org/10.1039/C0CC04567E
Article type
Communication
Submitted
22 Oct 2010
Accepted
14 Dec 2010
First published
11 Jan 2011

Chem. Commun., 2011,47, 2006-2007

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The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product

C. M. Mömming, G. Kehr, R. Fröhlich and G. Erker, Chem. Commun., 2011, 47, 2006 DOI: 10.1039/C0CC04567E

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