Issue 10, 2011
From the journal:

Chemical Communications

Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid†

Stephan Bernt,a   Vincent Guillerm,b   Christian Serreb  and  Norbert Stock*a  

* Corresponding authors

a Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, 24118 Kiel, Germany
E-mail: stock@ac.uni-kiel.de
Fax: +49 431 8801775
Tel: +49 431 8801675

b Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles Saint-Quentin, France

Abstract

For the first time, functionality has been covalently introduced into the Cr-MIL-101 network by post-synthetic modification of the terephthalate linker molecule through nitration. The nitro group was reduced and the amino group was reacted with ethyl isocyanate to yield the corresponding urea derivative.

Graphical abstract: Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid

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Article information

DOI
https://doi.org/10.1039/C0CC04526H
Article type
Communication
Submitted
20 Oct 2010
Accepted
07 Jan 2011
First published
21 Jan 2011

Chem. Commun., 2011,47, 2838-2840

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Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid

S. Bernt, V. Guillerm, C. Serre and N. Stock, Chem. Commun., 2011, 47, 2838 DOI: 10.1039/C0CC04526H

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