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Abstract | Cited by

Treatment of arylacetylenes and cyanogen bromide in ClCH2CH2Cl with a catalytic amount of GaCl3 afforded (Z)-β-bromoacrylonitriles with high regio- and stereoselectivity.

Graphical abstract: Gallium (iii)-catalysed bromocyanation of alkynes: regio- and stereoselective synthesis of β-bromo-α,β-unsaturated nitriles

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