Issue 5, 2011
From the journal:

Chemical Communications

Activation of a water molecule under mild conditions by ruthenacyclopentatriene: mechanism of hydrative cyclization of diynes†

Yoshihiko Yamamoto,*a   Ken Yamashitaa  and  Hisao Nishiyamaa  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan
E-mail: yamamoto@apchem.nagoya-u.ac.jp
Fax: +81 52 789 3209
Tel: +81 52 789 3337

Abstract

A ruthenium cyclic biscarbene complex reacted with a H2O molecule under mild conditions to produce η5-oxapentadienyl complex, that proved to be the intermediate in the catalytic hydrative cyclization of a diyne.

Graphical abstract: Activation of a water molecule under mild conditions by ruthenacyclopentatriene: mechanism of hydrative cyclization of diynes

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Article information

DOI
https://doi.org/10.1039/C0CC04345A
Article type
Communication
Submitted
11 Oct 2010
Accepted
11 Nov 2010
First published
29 Nov 2010

Chem. Commun., 2011,47, 1556-1558

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Activation of a water molecule under mild conditions by ruthenacyclopentatriene: mechanism of hydrative cyclization of diynes

Y. Yamamoto, K. Yamashita and H. Nishiyama, Chem. Commun., 2011, 47, 1556 DOI: 10.1039/C0CC04345A

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