Issue 6, 2011
From the journal:

Chemical Communications

Electrochemical meso-functionalization of magnesium(ii) porphine†

Charles H. Devillers,*a   Abdou K. D. Dime,a   Hélène Catteya  and  Dominique Lucas*a  

* Corresponding authors

a Institut de Chimie Moléculaire de l'Université de Bourgogne, UMR CNRS 5260, Université de Bourgogne, BP 47870, 21078 DIJON Cedex, France
E-mail: charles.devillers@u-bourgogne.fr, dominique.lucas@u-bourgogne.fr

Abstract

Regioselective meso-functionalization of the totally unsubstituted magnesium(II) porphine was performed by controlled potential electrolysis with pyridine and triphenylphosphine as nucleophiles leading to the original pyridinium and phosphonium substituted derivatives, respectively. The crystallographic structure of the latter is described as the only meso-phosphonium porphyrin reported to date.

Graphical abstract: Electrochemical meso-functionalization of magnesium(ii) porphine

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Article information

DOI
https://doi.org/10.1039/C0CC04309E
Article type
Communication
Submitted
08 Oct 2010
Accepted
18 Nov 2010
First published
06 Dec 2010

Chem. Commun., 2011,47, 1893-1895

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Electrochemical meso-functionalization of magnesium(II) porphine

C. H. Devillers, A. K. D. Dime, H. Cattey and D. Lucas, Chem. Commun., 2011, 47, 1893 DOI: 10.1039/C0CC04309E

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