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The synthesis and characterization of core–shell Fe3O4@organic@Au nanoparticles displaying plasmonic behavior, high magnetism, and high relaxivity is presented. The incorporation of a thin organic layer between the two metals is crucial in maintaining the saturation magnetisation of the superparamagnetic core.

Graphical abstract: Fe3O4@organic@Au: core–shell nanocomposites with high saturation magnetisation as magnetoplasmonic MRI contrast agents

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