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A new oxapalladacycle 3 can be conveniently prepared via direct ortho palladation of diphenylphosphinic acid with palladium acetate. Catalysts derived from 3 can efficiently catalyze Markovnikov-type additions of E–H bonds (P(O)–H, S–H and spC–H) to alkynesvia a unique catalytic cycle.

Graphical abstract: A new oxapalladacycle generated via ortho C–H activation of phenylphosphinic acid: an efficient catalyst for Markovnikov-type additions of E–H bonds to alkynes

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