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Issue 5, 2011
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An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation

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Abstract

After controlled pretreatment, some Zr-terephthalate metal–organic frameworks are highly selective catalysts for the cross-aldol condensation between benzaldehyde and heptanal. The proximity of Lewis acid and base sites in the amino-functionalized UiO-66(NH2) material further raises the reaction yields.

Graphical abstract: An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation

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Article information


Submitted
04 Aug 2010
Accepted
22 Oct 2010
First published
19 Nov 2010

Chem. Commun., 2011,47, 1521-1523
Article type
Communication

An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation

F. Vermoortele, R. Ameloot, A. Vimont, C. Serre and D. De Vos, Chem. Commun., 2011, 47, 1521
DOI: 10.1039/C0CC03038D

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