We propose herein an alternative biosynthetic pathway for palau'amine in order to resolve the stereochemical issue from the original Kinnel–Scheuer hypothesis. Furthermore, we use this revised hypothesis as a guide toward the laboratory synthesis of palau'amine.
Z. Ma, J. Lu, X. Wang and C. Chen, Chem. Commun., 2011, 47, 427 DOI: 10.1039/C0CC02214D
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