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Issue 1, 2011

Electron induced dissociation (EID) tandem mass spectrometry of octaethylporphyrin and its iron(iii) complex

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Abstract

EID tandem mass spectrometry of singly-charged electrosprayed ions of octaethylporphyrin (OEP) and its iron(III) complex results in ionisation to give doubly-charged precursor and fragment ions. Singly-charged fragments are also observed. EID fragmentation differs significantly to that observed in electron ionisation mass spectrometry.

Graphical abstract: Electron induced dissociation (EID) tandem mass spectrometry of octaethylporphyrin and its iron(iii) complex

Article information


Submitted
29 Jun 2010
Accepted
27 Aug 2010
First published
17 Sep 2010

Chem. Commun., 2011,47, 418-420
Article type
Communication

Electron induced dissociation (EID) tandem mass spectrometry of octaethylporphyrin and its iron(III) complex

M. A. Kaczorowska and H. J. Cooper, Chem. Commun., 2011, 47, 418 DOI: 10.1039/C0CC02198A

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