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Issue 1, 2011
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A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

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Abstract

A new D2A-type charge-transfer three-dimensional network with a charge distribution of [{Ru2}δ+–(BTDA-TCNQ2δ)–{Ru2}δ+] where δ ≈ 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(II, II) complex ([Ru2]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).

Graphical abstract: A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

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Supplementary files

Article information


Submitted
23 Jun 2010
Accepted
14 Jul 2010
First published
17 Aug 2010

Chem. Commun., 2011,47, 271-273
Article type
Communication

A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations

H. Miyasaka, T. Morita and M. Yamashita, Chem. Commun., 2011, 47, 271
DOI: 10.1039/C0CC02031A

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