Issue 1, 2011
From the journal:

Chemical Communications

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates†

Teresa de Haroa  and  Cristina Nevado*a  

* Corresponding authors

a Organic Chemistry Institute, University of Zürich, Winterthurerstrasse 190, Switzerland
E-mail: nevado@oci.uzh.ch
Tel: +41 4463 53975

Abstract

A combination of IPrAuNTf2 as catalyst in the presence of Selectfluor has been successfully used for the high yielding synthesis of α-fluoroenones via 1,3-acyloxy rearrangement of propargyl acetates followed by Csp2–F bond formation, likely involving a redox Au(I)/Au(III) catalytic cycle.

Graphical abstract: Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

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Article information

DOI
https://doi.org/10.1039/C002679D
Article type
Communication
Submitted
10 Feb 2010
Accepted
28 May 2010
First published
29 Jun 2010

Chem. Commun., 2011,47, 248-249

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Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

T. de Haro and C. Nevado, Chem. Commun., 2011, 47, 248 DOI: 10.1039/C002679D

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