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Issue 7, 2011
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Porphyrin–hexaphyrin hybrid tapes

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Abstract

A meso-meso linked porphyrin–hexaphyrin hybrid was synthesized by the cross condensation using meso-porphyrinyl-dipyrromethane and was oxidized with DDQ-Sc(OTf)3 to afford a porphyrin–[26]hexaphyrin hybrid tape that was reduced with NaBH4 to give a porphyrin–[28]hexaphyrin hybrid tape. Fully electronic conjugations in the hybrid tapes are observed in the UV/vis/NIR absorption spectra, electrochemistry, and excited-state dynamics.

Graphical abstract: Porphyrin–hexaphyrin hybrid tapes

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Publication details

The article was received on 08 Apr 2011, accepted on 28 Apr 2011 and first published on 19 May 2011


Article type: Edge Article
DOI: 10.1039/C1SC00228G
Chem. Sci., 2011,2, 1414-1418

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    Porphyrin–hexaphyrin hybrid tapes

    T. Tanaka, N. Aratani, J. M. Lim, K. S. Kim, D. Kim and A. Osuka, Chem. Sci., 2011, 2, 1414
    DOI: 10.1039/C1SC00228G

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