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Issue 4, 2011
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A β-to-β2,5-thienylene-bridged cyclic porphyrin tetramer: its rational synthesis and 1 : 2 binding mode with C60

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Abstract

A β-to-β2,5-thienylene-bridged cyclic porphyrin tetramer was rationally synthesized via a concise synthetic route. The tetraporphyrin exhibits a positive cooperative binding ability to C60 and demonstrates a new potential of the nonplanar, distorted cyclic porphyrin arrays.

Graphical abstract: A β-to-β2,5-thienylene-bridged cyclic porphyrin tetramer: its rational synthesis and 1 : 2 binding mode with C60

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Publication details

The article was received on 02 Dec 2010, accepted on 05 Jan 2011 and first published on 24 Jan 2011


Article type: Edge Article
DOI: 10.1039/C0SC00605J
Chem. Sci., 2011,2, 748-751

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    A β-to-β2,5-thienylene-bridged cyclic porphyrin tetramer: its rational synthesis and 1 : 2 binding mode with C60

    J. Song, N. Aratani, H. Shinokubo and A. Osuka, Chem. Sci., 2011, 2, 748
    DOI: 10.1039/C0SC00605J

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