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Issue 3, 2011
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Carbonate-coordinated metal complexes precede the formation of liquid amorphous mineral emulsions of divalent metal carbonates

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Abstract

During the mineralisation of metal carbonates MCO3 (M = Ca, Sr, Ba, Mn, Cd, Pb) liquid-like amorphous intermediates emerge. These intermediates that form via a liquid/liquid phase separation behave like a classical emulsion and are stabilized electrostatically. The occurrence of these intermediates is attributed to the formation of highly hydrated networks whose stability is mainly based on weak interactions and the variability of the metal-containing pre-critical clusters. Their existence and compositional freedom are evidenced by electrospray ionization mass spectrometry (ESI-MS). Liquid intermediates in non-classical crystallisation pathways seem to be more common than assumed.

Graphical abstract: Carbonate-coordinated metal complexes precede the formation of liquid amorphous mineral emulsions of divalent metal carbonates

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Article information


Submitted
12 Oct 2010
Accepted
25 Nov 2010
First published
10 Jan 2011

Nanoscale, 2011,3, 1158-1165
Article type
Paper

Carbonate-coordinated metal complexes precede the formation of liquid amorphous mineral emulsions of divalent metal carbonates

S. E. Wolf, L. Müller, R. Barrea, C. J. Kampf, J. Leiterer, U. Panne, T. Hoffmann, F. Emmerling and W. Tremel, Nanoscale, 2011, 3, 1158
DOI: 10.1039/C0NR00761G

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