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Issue 27, 2011
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Nanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium batteries

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Abstract

Highly stable LiV3O8 with a nanosheet-structure was successfully prepared using polyethylene glycol (PEG) polymer in the precursor solution as the structure modifying agent, followed by calcination in air at 400 °C, 450 °C, 500 °C, and 550 °C. These materials provide the best electrochemical performance ever reported for LiV3O8 crystalline electrodes, with a specific discharge capacity of 260 mAh g−1 and no capacity fading over 100 cycles at 100 mA g−1. The excellent cyclic stability and high specific discharge capacity of the material are attributed to the novel nanosheets structure formed in LiV3O8. These LiV3O8 nanosheets are good candidates for cathode materials for high-energy lithium battery applications.

Graphical abstract: Nanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium batteries

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Publication details

The article was received on 07 Mar 2011, accepted on 13 Apr 2011 and first published on 27 May 2011


Article type: Paper
DOI: 10.1039/C1JM10976F
J. Mater. Chem., 2011,21, 10077-10084

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    Nanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium batteries

    A. Pan, J. Zhang, G. Cao, S. Liang, C. Wang, Z. Nie, B. W. Arey, W. Xu, D. Liu, J. Xiao, G. Li and J. Liu, J. Mater. Chem., 2011, 21, 10077
    DOI: 10.1039/C1JM10976F

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