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Issue 10, 2011
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Combining alloy scattering of phonons and resonant electronic levels to reach a high thermoelectric figure of merit in PbTeSe and PbTeS alloys

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Abstract

The effect of the resonant impurity Tl, known to produce a high thermoelectric figure of merit in PbTe through a distortion of the density of states (DOS), is explored here in p-type PbTe1−xSx and PbTe1−ySey alloys with direct substitution of Tl for Pb, with the goal of combining its effect with a reduction of the thermal conductivity by alloy scattering. In PbTe1−xSx, the high DOS of PbTe:Tl (x = 0) is maintained up to x = 0.08, whereas the samples' mobility surprisingly increases monotonically with x. An optimal composition is found to reach zT = 1.6 at x = 0.08, using double-doping with both Tl and Na. The DOS of all PbTe1−ySey alloys decreases with y > 0. KKR-CPA electronic structure calculations were performed to enlighten the experimental trends in transport properties: thallium triggers the formation of free-electron-like excess DOS near Fermi level by coupling a Tl 6s-level to the Te p-levels. We ascribe the loss of resonant behavior to a change in overlap between these two levels due to the decrease of the lattice constant with x and y.

Graphical abstract: Combining alloy scattering of phonons and resonant electronic levels to reach a high thermoelectric figure of merit in PbTeSe and PbTeS alloys

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Article information


Submitted
05 Jun 2011
Accepted
14 Jul 2011
First published
10 Aug 2011

Energy Environ. Sci., 2011,4, 4155-4162
Article type
Paper

Combining alloy scattering of phonons and resonant electronic levels to reach a high thermoelectric figure of merit in PbTeSe and PbTeS alloys

C. M. Jaworski, B. Wiendlocha, V. Jovovic and J. P. Heremans, Energy Environ. Sci., 2011, 4, 4155
DOI: 10.1039/C1EE01895G

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