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Issue 35, 2011
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Peripherally cyclometalated iridium complexes of dipyridylporphyrin

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Abstract

Two types of novel iridium pincer complexes bearing a porphyrin backbone were synthesized and characterized from dipyridylporphyrin. One of the complexes has a Lewis acidic site on the iridium center in the mer-coordination mode. The other complex takes the fac-coordination, which is rarely observed in benzene-based pincer complexes.

Graphical abstract: Peripherally cyclometalated iridium complexes of dipyridylporphyrin

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Publication details

The article was received on 14 Feb 2011, accepted on 11 Apr 2011 and first published on 03 May 2011


Article type: Communication
DOI: 10.1039/C1DT10246J
Dalton Trans., 2011,40, 8773-8775

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    Peripherally cyclometalated iridium complexes of dipyridylporphyrin

    K. Yoshida, T. Nakashima, S. Yamaguchi, A. Osuka and H. Shinokubo, Dalton Trans., 2011, 40, 8773
    DOI: 10.1039/C1DT10246J

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