Unique trigonal prism encapsulated Ln complexes: a [CoII6Eu] and a [CoII6Dy] cage

Maria Orfanoudaki; Ioannis Tamiolakis; Milosz Siczek; Tadeusz Lis; Gerasimos S. Armatas; Spiros A. Pergantis; Constantinos J. Milios

doi:10.1039/C1DT10052A

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Unique trigonal prism encapsulated Ln complexes: a [Co^II₆Eu] and a [Co^II₆Dy] cage†

Maria Orfanoudaki,^a Ioannis Tamiolakis,^b Milosz Siczek,^c Tadeusz Lis,^c Gerasimos S. Armatas,^b Spiros A. Pergantis^a and Constantinos J. Milios*^a

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* Corresponding authors

^a Department of Chemistry, The University of Crete, Voutes, Herakleion, Greece
E-mail: komil@chemistry.uoc.gr

^b Department of Materials Science, The University of Crete, Voutes, Herakleion, Greece

^c Faculty of Chemistry, The University of Wroclaw, Joliot-Curie 14, Wroclaw, Poland

Abstract

The use of 2-amino-isobutyric acid in Co/Ln chemistry has led to the isolation of two unique [Co^II₆Ln^III] 3d-4f metallic cages in which the Ln^III centre (Ln = Eu, Dy) is encapsulated within a Co^II₆ trigonal prism.

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Article information

DOI: https://doi.org/10.1039/C1DT10052A
Article type: Communication
Submitted: 12 Jan 2011
Accepted: 21 Feb 2011
First published: 11 Mar 2011

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Dalton Trans., 2011,40, 4793-4796

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Unique trigonal prism encapsulated Ln complexes: a [Co^II₆Eu] and a [Co^II₆Dy] cage

M. Orfanoudaki, I. Tamiolakis, M. Siczek, T. Lis, G. S. Armatas, S. A. Pergantis and C. J. Milios, Dalton Trans., 2011, 40, 4793 DOI: 10.1039/C1DT10052A

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