A new oxime ligand in manganese chemistry: a [Mn8] and a [Mn6] cage from the use of 2-dihydroxy-2-phenylacetamidine

Andreas G. Flamourakis; Demetrios Tzimopoulos; Milosz Siczek; Tadeusz Lis; James R. O'Brien; Pericles D. Akrivos; Constantinos J. Milios

doi:10.1039/C1DT11455G

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A new oximeligand in manganese chemistry: a [Mn₈] and a [Mn₆] cage from the use of 2-dihydroxy-2-phenylacetamidine†

Andreas G. Flamourakis,^a Demetrios Tzimopoulos,^b Milosz Siczek,^c Tadeusz Lis,^c James R. O'Brien,^d Pericles D. Akrivos^b and Constantinos J. Milios*^a

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* Corresponding authors

^a Department of Chemistry, University of Crete, Herakleion, Greece
E-mail: komil@chemistry.uoc.gr
Tel: +30-2810-545099

^b Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, Greece

^c Faculty of Chemistry, Joliot-Curie 14, Wroclaw, Poland

^d Quantum Design, San Diego, CA, USA

Abstract

The use of phamidoxH₂ (phamidoxH₂ = 2-dihydroxy-2-phenylacetamidine) in manganese cluster chemistry led to the synthesis and characterization of a hexametallic and an octametallic Mn^III cluster, both of which display a S = 3 ground state.

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Article information

DOI: https://doi.org/10.1039/C1DT11455G
Article type: Communication
Submitted: 02 Aug 2011
Accepted: 02 Sep 2011
First published: 29 Sep 2011

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Dalton Trans., 2011,40, 11371-11373

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A new oxime ligand in manganese chemistry: a [Mn₈] and a [Mn₆] cage from the use of 2-dihydroxy-2-phenylacetamidine

A. G. Flamourakis, D. Tzimopoulos, M. Siczek, T. Lis, J. R. O'Brien, P. D. Akrivos and C. J. Milios, Dalton Trans., 2011, 40, 11371 DOI: 10.1039/C1DT11455G

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Dalton Transactions