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Issue 18, 2011
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Enhancing Ueff in oxime-bridged [MnIII6LnIII2] hexagonal prisms

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Abstract

The first 3d-4f clusters built using derivatised salicylaldoximes (R-saoH2) describe unusual hexagonal prisms. Replacement of the paramagnetic Gd(III) ions with diamagnetic Ln(III) ions allows for a more thorough understanding of the magnetic properties, whilst replacement with Tb(III) doubles Ueff.

Graphical abstract: Enhancing Ueff in oxime-bridged [MnIII6LnIII2] hexagonal prisms

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Article information


Submitted
27 Jan 2011
Accepted
11 Mar 2011
First published
29 Mar 2011

Dalton Trans., 2011,40, 4797-4799
Article type
Communication

Enhancing Ueff in oxime-bridged [MnIII6LnIII2] hexagonal prisms

G. Rigaux, R. Inglis, S. Morrison, A. Prescimone, C. Cadiou, M. Evangelisti and E. K. Brechin, Dalton Trans., 2011, 40, 4797
DOI: 10.1039/C1DT10154D

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