Enhancing Ueff in oxime-bridged [MnIII6LnIII2] hexagonal prisms

Guillaume Rigaux; Ross Inglis; Susan Morrison; Alessandro Prescimone; Cyril Cadiou; Marco Evangelisti; Euan K. Brechin

doi:10.1039/C1DT10154D

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Enhancing U_eff in oxime-bridged [Mn^III₆Ln^III₂] hexagonal prisms†

Guillaume Rigaux,^ab Ross Inglis,^b Susan Morrison,^b Alessandro Prescimone,^b Cyril Cadiou,^a Marco Evangelisti*^c and Euan K. Brechin*^b

Author affiliations

* Corresponding authors

^a Université de Reims Champagne-Ardenne, Institut de Chimie Moléculaire de Reims (ICMR), Groupe Chimie de Coordination, CNRS UMR 6229, Bât. Europol'Agro - Moulin de la Housse, Reims cedex 2, France

^b EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, (UK)
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: (+44)131-650-6453

^c Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Departamento de Física de la Materia Condensada, Zaragoza, Spain
E-mail: evange@unizar.es

Abstract

The first 3d-4f clusters built using derivatised salicylaldoximes (R-saoH₂) describe unusual hexagonal prisms. Replacement of the paramagnetic Gd(III) ions with diamagnetic Ln(III) ions allows for a more thorough understanding of the magnetic properties, whilst replacement with Tb(III) doubles U_eff.

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Supplementary files

Crystal structure data TXT (174K)

Article information

DOI: https://doi.org/10.1039/C1DT10154D
Article type: Communication
Submitted: 27 Jan 2011
Accepted: 11 Mar 2011
First published: 29 Mar 2011

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Dalton Trans., 2011,40, 4797-4799

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Enhancing U_eff in oxime-bridged [Mn^III₆Ln^III₂] hexagonal prisms

G. Rigaux, R. Inglis, S. Morrison, A. Prescimone, C. Cadiou, M. Evangelisti and E. K. Brechin, Dalton Trans., 2011, 40, 4797 DOI: 10.1039/C1DT10154D

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Dalton Transactions