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Issue 15, 2011
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Highly active and tunable catalysts for O2 evolution from water based on mononuclear ruthenium(ii) monoaquo complexes

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Abstract

The catalytic activity of [Ru(tpy)(bpy)OH2]2+ (tpy = 2,2′:6′,2′′-terpyridine and bpy = 2,2′-bipyridine) increased by a 4′-substituted ethoxy group on the tpy ligand by more than one order of magnitude to give 1.1 × 10−1s−1 of catalyst turnover frequency, which is comparable with the hitherto-reported champion data.

Graphical abstract: Highly active and tunable catalysts for O2 evolution from water based on mononuclear ruthenium(ii) monoaquo complexes

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Supplementary files

Article information


Submitted
24 Dec 2010
Accepted
14 Jan 2011
First published
31 Jan 2011

Dalton Trans., 2011,40, 3802-3804
Article type
Communication

Highly active and tunable catalysts for O2 evolution from water based on mononuclear ruthenium(II) monoaquo complexes

M. Yagi, S. Tajima, M. Komi and H. Yamazaki, Dalton Trans., 2011, 40, 3802
DOI: 10.1039/C0DT01826K

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