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Issue 9, 2011
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Miceller media accelerated Baylis–Hillman reaction

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Abstract

Triton X-100 aqueous micelle accelerates the rate of Baylis–Hillman reaction and enhances the product yield. The type and concentration of surfactants play prominent roles in the reaction. An aqueous micelle Triton X-100 is easily recovered and reused for four runs without substantial loss in yield. 1,4-diazabicyclo[2.2.2]octane (DABCO) (20 mol%) is found to be a good basic catalyst in aqueous micelle. Apparently, this protocol has several advantages such as green reaction medium, mild reaction condition, ease of product recovery and moderate-to-good yield of product.

Graphical abstract: Miceller media accelerated Baylis–Hillman reaction

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Publication details

The article was received on 16 Jul 2011, accepted on 22 Aug 2011 and first published on 16 Sep 2011


Article type: Communication
DOI: 10.1039/C1CY00278C
Catal. Sci. Technol., 2011,1, 1641-1644

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    Miceller media accelerated Baylis–Hillman reaction

    B. Pawar, V. Padalkar, K. Phatangare, S. Nirmalkar and A. Chaskar, Catal. Sci. Technol., 2011, 1, 1641
    DOI: 10.1039/C1CY00278C

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