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Issue 10, 2011
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Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

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Abstract

Palladium-catalyzed carbonylative coupling reactions of aromatic halides and related compounds have undergone a rapid development during recent years. Nowadays, a plethora of palladium catalysts are available for the synthesis of ketones, alkynones, chalcones, etc., which are important intermediates in the manufacture of dyes, pharmaceuticals, agrochemicals, and other industrial products. In this critical review, we summarize the development of these carbonylative transformations with carbon nucleophiles (136 references).

Graphical abstract: Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

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Article information


Submitted
20 Apr 2011
First published
27 Jul 2011

Chem. Soc. Rev., 2011,40, 4986-5009
Article type
Critical Review

Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

X. Wu, H. Neumann and M. Beller, Chem. Soc. Rev., 2011, 40, 4986 DOI: 10.1039/C1CS15109F

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